有机-无机催化材料组
Hybrid Organic-Inorganic Materials for Catalysis
 

杨启华 (QiHua Yang)
研究员 博士生导师
(Professor, Ph.D.)

电话:+86-411-84379552
传真:+86-411-84694447
Email: yangqh@dicp.ac.cn
Web: http://www.hmm.dicp.ac.cn

 

理学博士,研究员,博士生导师, 1997 东北师范大学化学系获博士学位。1999-2003 分别在大连化学物理研究所国家基础重点实验室,法国国家科学院LCOMS-CNRS/CPE实验室及日本豐田中央研究所进行博士后研究。

主要学术任职:

辽宁师范大学兼职教授、功能材料化学研究所学术委员会委员

<<石油化工>>编委会委员

<<无机材料学报>>编委会委员

获得奖励:

第十二届国际催化大会奖(12th ICC Congress Prize,2000,西班牙)

第九届全国青年催化学术会议优秀论文一等奖 (2003,上海)

2002年入选中国科学院“百人工程”

2007年获第六届辽宁青年科技奖

主要研究领域:

二十一世纪是材料化学的时代,在新兴领域如纳米技术及生物工程中不断需要具有不同物理和化学性能的新材料。单一组成物种制备的材料很难同时满足各种需要。有机-无机杂化材料是一类功能复合材料,其性质主要取决于材料各微观组分的性质以及各组分间相互结合的方式。针对不同应用背景实现材料结构和功能的定向控制合成是材料领域的研究热点和难点。我们通过在分子以及纳米尺度上对材料结构单元以及各单元间的结合方式的精细调变进行有机-无机杂化材料的可控合成研究并开展它们在催化、分离及生物等领域的应用研究。目前主要开展的研究方向有:

1)有机-无机多孔催化材料的合成方法研究;2)有机-无机手性纳米孔材料的合成及其在多相不对称催化及手性拆分中的性能研究;3)新型固体酸催化剂的设计、合成及酸催化性能研究;4)固载酶及酶催化研究;5)新型有机-无机杂化光电复合材料。
Prof. Qihua Yang (born: 1969, Yantai, China) began her research career in State Key Laboratory of Catalysis, Dalian Institute of Chemistry in 1997 as a Post-doc.
After that she worked as a visiting scholar in France and Japan, respectively. Now she is a professor in “Hybrid Organic-Inorganic Materials for Catalysis” group. The topics of the group: Synthesis and applications of organic- inorganic hybrid materials. The strategies for the synthesis of organic-inorganic materials involves the supramolecular synthesis of periodic mesoporous organosilicas, Sol-gel synthesis of hybrid organic-inorganic armorphous materials, and surface organometallic synthesis of organometallic complex functionalized materials.
The applications of the hybrid organic-inorganic materials include catalytic production of fine chemicals; heterogeneous asymmetric catalysis and heavy metal adsorbents.
Research focuses are thus placed on:
1. Sponge biomedicine, biosilica and cell biosensor, which are based on cell cultivation.
2. R&D of bio-hydrogen from marine green alga.

 
代表性文章 REPRESENTATIVE PUBLICATIONS
1.

Q. H. Yang, M. P. Kapoor and S. Inagaki, Sulfuric acid-functionalized mesoporous benzene-silica with a molecular-scale periodicity in the walls, J. Am. Chem. Soc., 124, 9694-9695 (2002)

2.

Q. H. Yang, J. Liu, J. Yang, M. P. Kapoor, S. Inagaki and C. Li, Synthesis, characterization and catalytic activity of sulfonic acid-functionalized periodic mesoporous organosilicas, J. Catal., 228, 265-272 (2004)

3.
J. Liu, J. Yang, Q. H. Yang, G. Wang and Y. Li, Hydrothermally stable thioether-bridged mesoporous materials with void defects in the pore wall, Adv. Funct. Mater., 15, 1297-1302 (2005)
4.
L. Zhang, H. C. L. Abbenhuis, Q. H. Yang, Y. M. Wang, P. C. M. M. Magusin, B. Mezari, R. A. van Santen, C. Li,Mesoporous organic-Inorganic hybrid materials built using polyhedral oligomeric silsesquioxane blocks, Angew. Chem. Int. Ed., 46, 5003-5006 (2007)
5. H. Yang, L. Zhang, L. Zhong, Q. H. Yang, C. Li, Enhanced cooperative activation effect in the hydrolytic kinetic resolution of epoxides on [Co(salen)] catalysts confined in nanocages, Angew. Chem. Int. Ed., 46, 6861 –6865 (2007)